Show Toolbar/Address Bar on Hover While in True Full Screen

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I have this same problem.

cmd+shift+F toggles the toolbar in fullscreen, but it does not make the toolbar appear only on hover, as OP queried.

Big Sur 11.4 Brave Version 1.25.73 Chromium: 91.0.4472.106 (Official Build) (x86_64)

Cannot create new tab in full screen